what is phosphine gas

Commercial grade phosphine derived from aluminum or magnesium phosphide can contain to a variable degree higher molecular weight phosphines including diphosphines. This summer, before the phosphine announcement, she and her co-authors published a speculative, hypothetical sketch of what life on Venus could look like. Phosgene is a valued industrial building block, especially for the production of urethanes and polycarbonate plastics. On Earth, this gas is only made industrially or by microbes that thrive in oxygen-free environments. What does this mean? Something deadly might be wafting through the clouds shrouding Venus—a smelly, flammable gas called phosphine that annihilates life-forms reliant on … Odor is not an adequate indicator of phosphine's presence and may not provide reliable warning of hazardous concentrations. It is the simplest gas that has phosphorus on it; the phosphorus equivalent of ammonia (for nitrogen), methane (for carbon) and water (for oxygen). Methods: This is a case report and a review of literature. As exposure deadens the sense of smell, do not use smell to determine phosphine concentration. DESCRIPTION: Phosphine is used in the semiconductor industry to introduce phosphorus into silicon crystals . The unpleasant odor arises due to the presence of substituted phosphine and diphosphane. Its toxicity and oxidation state in terms of other phosphorus related substances is shown below. An air concentration of 3 ppm is safe for long term exposure, 500 ppm is lethal in 30 minutes, and a concentration of 1,000 ppm is lethal after a few breaths. La phosphine [a], hydrure de phosphore, phosphure d'hydrogène, ou phosphane (nomenclature IUPAC) est un composé inorganique du phosphore et de l'hydrogène, de formule PH 3.. À température et pression ordinaires, la phosphine est un gaz hautement écotoxique, phytotoxique [13], hautement toxique pour les mammifères (dont l'être humain), et « pour lequel il n'existe pas d'antidote » [14]. Phosphine is a poisonous gas. “Phosphine is a colorless, flammable, and explosive gas at ambient temperature that has the odor of garlic or decaying fish,” the National Library … Heating phosphine c… The vision is beautiful: a … Phosphine gas is a molecule made up of one phosphorus atom and three hydrogen atoms. (1,3) The international team of scientists reported traces of phosphine in concentration of approximately 20 parts per billion, thousands to millions of times more than what could otherwise be expected. Phosphine is formed by the action of a strong base or hot water on white phosphorus or by the reaction of water with calcium phosphide (Ca 3 P 2 ). Objective: The objective of the study was to report the toxicity of phosphine gas after a residential fumigation that resulted in fatal poisoning of a 15-month-old toddler and her 4-year-old sibling. It is a colourless, flammable, very toxic gas made up of phosphorous and hydrogen. 1 Part 1 | Various. However, it can dissolve in natural solvents. Phosphine is used as an insecticide for the fumigation of grains, animal feed, and leaf-stored tobacco, and as a rodenticide. A chemical we haven’t heard of before is in the news thanks Scientists announce the discovery of phosphine, which they say may be a sign of life in the clouds of Venus, Which is a confusing g… Phosphine is an inorganic compound having the chemical formula PH 3. Here's why the latest discovery by astronomers has triggered excitement. On Earth, this gas is only made industrially or by microbes that thrive in oxygen-free environments. 1 : a colorless poisonous flammable gas PH3 that is a weaker base than ammonia and that is used especially to fumigate stored grain. Phosphine (PH 3) is found here on Earth, as well as on the Solar System’s gas giants. Updates? The unpleasant odor arises due to the presence of substituted phosphine and diphosphane. Phosphine is an inorganic compound having the chemical formula PH 3. Phosphine is structurally similar to ammonia (NH 3 ), but phosphine is a much poorer solvent than ammonia and is much less … Phosphine is spontaneously flammable creating toxic fumes. It often reacts with air. 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This may be a conservative value due to the lack of relevant acute toxicity data for workers exposed to concentrations above 35 ppm. Our editors will review what you’ve submitted and determine whether to revise the article. Phosphine gas is formed by heating white phosphorus with concentrated caustic soda. It is highly poisonous gas. Physical and chemical properties of phosphine: It is a colourless gas having a rotten fish smell. * The moderation of comments is automated and not cleared manually by, Copyright © 2020 The Indian Express [P] Ltd. All Rights Reserved, Quixplained: What discovery of phosphine gas in the atmosphere of Venus means. At high concentrations, phosphine vapors may spontaneously combust in air. In any case, pure phosphine is actually odorless; an impurity, diphosphane (P 2 H 4), is responsible for its foul scent. It is very poisonous and was used as a chemical weapon during World War I, when it was responsible for 85,000 deaths. Phosphine is also released by aluminum phosphide and magnesium phosphide. An international team of researchers have detected traces of phosphine gas in the atmosphere of Venus. Thus, methylphosphine (CH3PH2) is a primary phosphine, in which the methyl group (CH3) takes the place of one of the hydrogen atoms of phosphine itself. Structure of Phosphine. The entire molecular structure of Phosphine is a trigonal pyramid. Commercial grade phosphine derived from aluminum or magnesium phosphide can contain to a variable degree higher molecular weight phosphines including diphosphines. Something deadly might be wafting through the clouds shrouding Venus—a smelly, flammable gas called phosphine that annihilates life-forms reliant on … Inhalation is the major route of phosphine toxicity. Phosphine definition, a colorless, poisonous, ill-smelling, flammable gas, PH3. Exposure to phosphine may cause, nausea, vomiting, stomach pain, diarrhea, thirst, muscle pain, difficulty breathing, and fluid in the lungs. This article was most recently revised and updated by, https://www.britannica.com/science/phosphine, Food and Agriculture Organization of the United Nations - Phosphine. Phosphine, the simplest phosphorus hydride, is a colorless and extremely toxic gas. Phosphine is a super- toxic gas with a probable oral lethal dose of 5 mg/kg or 7 drops for a 150 pound person. It is a colorless and flammable gas having a slightly unpleasant odor. Phosgene is the organic chemical compound with the formula COCl 2.It is a colorless gas; in low concentrations, its odor resembles that of freshly cut hay or grass. When rats swallow poison with zinc phosphide, it mixes with stomach acid and turns to phosphine gas. On Earth, phosphine is a flammable, foul, toxic gas produced by bacteria that doesn't require oxygen -- like those in swamps, wetlands, sludge or even animal guts… Thus, it … Phosphine (or PH₃) is a pyramid-shaped molecule with a single phosphorus atom on top, and a base formed of three hydrogen atoms. Life on Venus? Neither would one expect the traces of acetylene, ethane, and other hydrocarbons that have been detected in the stratosphere. Corrections? 2 : any of various derivatives of phosphine … Phosphine, at first glance, is a rather unremarkable molecule to find. Phosphine is a gas of … Results: A family of 6 members was exposed to phosphine gas after their yard was treated with aluminum phosphide for a rodent infestation. Phosphine, a colourless but smelly gas, is known to be made only by some species of bacteria that survive in the absence of oxygen. Phosphane ) is an unanticipated trace gas that is what is phosphine gas toxic at extremely low concentrations, odor! 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